Q = 0 --- PMM -1 --- w
PMM -1 is impossible.
dv = m.Cv.dT ,
dH = m.Cp.dT
Here U = f ( t )
Heat transfer -:
Heat transfer in various non - flow process--
1. Constant volume process -:
Heat transfer in a constant volume process for a closed system is equal to change in thermal energy .
dQ = du + P. dv
When , v = Constant, dv = 0 dw = 0
Then dQ = dv
2. Constant pressure process-:
Heat transfer for a constant pressure process is equal to change in Enthalpy.
dQ = du + P. dv
When , P = Constant
dQ = du + P ( dv ) , dQ = d ( u + Pv )
dQ = dH
3. Isothermal process-:
When an ideal gas undergoes isothermal process , heat transfer is equal to work .
dQ = du + P.dv
When , T = Constant if u = f ( t ) du = 0
dQ = dw .
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